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dc.contributor.authorMameri, Yazid
dc.contributor.authorDebbache, Nadra
dc.date.accessioned2019-01-23T11:04:12Z
dc.date.available2019-01-23T11:04:12Z
dc.date.issued2018-07-03
dc.identifier.urihttp://hdl.handle.net/123456789/136511
dc.description.abstractThe photodegradation of two pharmaceuticals (PP), paracetamol (PC) and aspirin (ASP), induced by an iron (III) oxyhydroxide (Goethite) was studied in aqueous solution in heterogeneous phase. The phototransformation of the substrates was followed by spectrophotometry and HPLC in various mixtures namely: PP-Goethite, PP-Goethite-H2O2 and PP-Goethite-carboxylic acid. In absence of light both substrates showed different behavior with regard to Goethite in aqueous solution. Indeed, no interaction was observed in the case of the PC whereas a particular reaction was highlighted in the case of the ASP. Under irradiation, photodegradation of PP induced by Goethite shows slow kinetics and is dependent on several parameters such as pH, substrate concentration and catalyst. Fe (II) formed exclusively in the ASP-Goethite mixture shows the photocatalytic dissolution of Goethite. The mechanistic study reveals that hydroxyl radicals are not involved in the photocatalytic process of PC, however they govern on the photodegradation mechanism of ASP. The addition of hydrogen peroxide in the PP-Goethite mixture improves significantly the rate of disappearance of the substrates following a large production of ●OH radicals generated by a heterogeneous photo Fenton reaction. Different parameters have been studied, the effect of pH, as well as the concentration of H2O2. The addition of carboxylic acid to the PP-Goethite system has also been studied and shows that oxalic acid has the most important photoactivity following the involvement of the heterogeneous like-Fenton process resulting from the photoreductive dissolution of the complex surface formed between Fe (III) of Goethite and oxalic acid. The following of the mineralization shows that the life of intermediates reaction is much greater than the starting product. In order to verify the feasibility of the photochemical process in the environment, the same systems were studied under solar irradiation. The results show that such systems operate with kinetics of the same order as those observed in artificial irradiations. These results provide some knowledge about the fate of PP in the aquatic environment as well as the photocatalytic treatment with oxy (hydroxides) of Fe (III). These results are very promising for the application of this system under pH conditions close to those met in the environment.fr_FR
dc.language.isofrfr_FR
dc.publisherجامعة الإخوة منتوري قسنطينةfr_FR
dc.subjectParacétamolfr_FR
dc.subjectAspirinefr_FR
dc.subjectPhotodégradationfr_FR
dc.subjectRadicaux hydroxylefr_FR
dc.subjectGoethitefr_FR
dc.subjectFentonfr_FR
dc.subjectParacetamolfr_FR
dc.subjectAspirinfr_FR
dc.subjectPhotodegradationfr_FR
dc.subjectHydroxyl radicalsfr_FR
dc.subjectالباراسيتامولfr_FR
dc.subjectالأسبرينfr_FR
dc.subjectالتفكك الضوئيfr_FR
dc.subjectجذور الهيدروكسيلfr_FR
dc.subjectفانتونfr_FR
dc.titleComportements thermique et photochimique du paracétamol et de l’aspirine par la goethite en solution aqueuse en phase hétérogènefr_FR
dc.typeThesisfr_FR


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