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dc.contributor.authorZebiri ép Benahmed, Ikram
dc.contributor.authorBencharif, Leïla
dc.date.accessioned2017-06-27T17:30:27Z
dc.date.available2017-06-27T17:30:27Z
dc.date.issued2017-03-09
dc.identifier.urihttp://hdl.handle.net/123456789/135706
dc.description.abstractThis work, consist to the study of the solid composition with dual character organicinorganic permits us to conclude the hybrid character of the given materials. This one appears in the structural organizations and the electronic properties observed. A part of this memory is about the preparation of new polyoxométallates by hydrothermal technic. We present three new compounds (TTF)8[Mo6O19]2(CH3CN), (C14H16N2)2 (C14H17N2)2(C14H18N2)[β-Mo8O26] and H[MoO3], exhibited a character semi-conductor confirmed by structural, spectroscopic and electro-chemical characterizations. To explain the electronic properties of different isopolyoxometalates. we have showed the correlation between the structural particularities of each one of isomers, and their electronic proprieties. The relation between the different values of the gap with the geometric structure observed was calculated by the functional of the density using GGA and LDA approximations.fr_FR
dc.language.isofrfr_FR
dc.subjectPolyoxométallatesfr_FR
dc.subjectcatalysefr_FR
dc.subjectélectrochimiefr_FR
dc.subjecthybridesfr_FR
dc.subjectDFTfr_FR
dc.subjectanisotropiefr_FR
dc.titleSynthèse, caractérisation, étude théorique dans le cadre de la DFT de nouveaux composés hybrides organiques – inorganiquesfr_FR
dc.typeThesisfr_FR


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